This strikingly handsome purple-leaved small tree with wispy flowers is found on the south side of the W&OD bike path immediately west of the American Dream Way bridge. There are several more specimens in the median between the W&OD bike path and the W&OD gravel path near the Fannie Mae Gardens.
This is a smoketree (Cotinus coggygria, see this Virginia Tech fact sheet, NC State fact sheet and this Wikipedia article), which is a relative of the sumacs
In a clearing south of the W&OD bike path across from the Fannie Mae Gardens is a thicket of this plant, whose flower resembles a small thistle but whose leaves and stems are far less spiny. This appears to be a knapweed (Centaurea spp.), and may be the highly invasive spotted knapweed (C. maculosa, see this Missouri description and this Wikipedia article).
Pokeweed (Phytolacca americana) is beginning to bloom, as here on the north side of the W&OD bike path near Isaac Newton Square; see this post from last September for how pokeweed appears once it fruits out.
A couple of small flowering plants hidden in the grass west of the W&OD bike path south of Sunset Hills Drive. The white five-petaled flower with prominent anthers appears to be Carolina horsenettle (Solanum carolinense), already featured before in this post from last October. The small pink-flowered plant next to it with the reddish stem and comparatively large lanceolate leaves appears to be some form of knotweed, perhaps tufted knotweed (Polygonum caespitosum, compare this Virginia Tech weed guide and this Connecticut description), even though the Digital Flora of Virginia does not list this species.
No doubt about this species - this is common milkweed (Asclepias syriaca), now bursting into flower in this thicket on the south side of the W&OD bike path across from the Fannie Mae Gardens.
Close-up of an inflorescence. Compare the Missouri description.
Milkweed flowers are apparently quite popular with insects. Here is a shot with two large butterflies feeding on separate inflorescences; these plants are located in the median between the W&OD bike path and the W&OD gravel path just south of Sunset Hills Drive and north of the Dulles Toll Road bridge.
And here is a shot with a bee of some sort.